Vol. 28 No. 3 (2025) Cover Image
Vol. 28 No. 3 (2025)

Published: September 30, 2025

Pages: 378-391

Articles

Using Zeolite as a Partially Replaced Cement in Construction Materials: A Systematic Review of Properties

Alaa M. Hamad 1 Asmaa T. Ibraheem 1 Ahmad S. Ali 1 Azza H. Moubarak 2
1 Department of Civil Engineering, Al-Nahrain University, Baghdad, Iraq.
2 Department of Civil Engineering, Suez Canal University, Ismailia, Egypt
History
  • Received: September 10, 2024
  • Revised: February 5, 2025
  • Accepted: February 17, 2025
  • Available Online: September 29, 2025
DOI

https://doi.org/10.29194/NJES.28030378

Abstract

Concrete is considered the most important and widely used building material in the world of construction and building due to its durability, high efficiency in shaping, and relatively reasonable cost. The main component of concrete is cement, and one of the most important problems related to cement is the environmental problems associated with cement manufacturing, as the cement manufacturing process releases a large amount of carbon dioxide. Despite the essential role of concrete in construction, we cannot ignore its environmental impact. Some claim that exploring alternative materials or innovative building techniques would reduce the carbon footprint and enhance sustainability in the industry. Partial cement replacement with pozzolanic materials like zeolite is a key technique to reduce carbon dioxide emissions. Zeolite, which reduces permeability, is a typical concrete ingredient that strengthens and lasts. Recently, natural zeolite has become a prominent concrete pozzolanic component. For environmental preservation and sustainable development, various experiments were done on concrete with pozzolanic components partially substituting cement and compared to ordinary concrete. A partial replacement of cement with zeolite improves the properties of concrete up to a certain age and mixing ratio. More than 44 relevant articles from 2004–2024 were selected from 762 papers evaluated for this paper. This paper reviews natural zeolite research in real applications. Additionally, it provided a cutting-edge review of natural zeolite literature through a critical analysis of various previous investigations. It also helped to understand how zeolite influences concrete mixture workability, strength, and durability. Since zeolite is a major concrete ingredient, it should be promoted as a sustainable resource.

Keywords

References

  1. P. K. Mehta and P. J. M. Mehta, Microstructure and properties of hardened concrete, Concrete: Microstructure, Properties and Materials, 2006.
  2. M. A. Bazyar, A. F. S. Bazyar and K. Shekarchi, "Natural zeolite as a supplementary cementitious material - A holistic review of main properties and applications," Constr. Build. Mater., p. 5, 2023.
  3. D. W. Breck and J. V. S. Breck, "Molecular sieves," Sci. Am., vol. 200, no. 1, pp. 85-96, 1959. DOI:10.1038/scientificamerican0159-85
  4. C. S. Lam, L. K. S. Choy and L. Z. S. Poon, "A study on the hydration rate of natural zeolite blended cement pastes," Constr. Build. Mater., pp. 427-432, 1999.DOI:10.1016/S0950-0618(99)00048-3
  5. F. Yilmaz, K. K. Mert, M. S. Mert and Y. M. A. Canpolat, "Use of zeolite, coal bottom ash and fly ash as replacement materials in cement production," Cem. Concr. Res., pp. 731-735, 2004. DOI:10.1016/S0008-8846(03)00063-2
  6. S. Wang and P. Y. Wang, "Natural zeolites as effective adsorbents in water and wastewater treatment," Chem. Eng. J., pp. 11-24, 2010. DOI:10.1016/j.cej.2009.10.029
  7. S. Yip and J. X. Chan, "Comparative study of the initial surface absorption and chloride diffusion of high performance zeolite, silica fume and PFA concretes," Cem. Concr. Compos., pp. 293-300, 1999. DOI:10.1016/S0958-9465(99)00010-4
  8. C. K. Ho and T. I. B. Karakurt, "Utilization of natural zeolite in aerated concrete production," Cem. Concr. Compos., pp. 1-8, 2010.
  9. I. Papayianni and A. Papayianni, "Production of high-strength concrete using high volume of industrial by-products," Constr. Build. Mater., pp. 1412-1417, 2010. DOI:10.1016/j.conbuildmat.2010.01.016
  10. M. Miah and I. M. S. Islam, "Strength and durability characteristics of concrete made with fly-ash blended cement," Aust. J. Struct. Eng., pp. 303-319, 2013.
  11. A. A. Mirmohseni, R. K. M. S. Jafari and R. Ramezanianpour, "Micro and macro level properties of natural zeolite contained concretes," 2015.
  12. F. A. Mumpton, Mineralogy and geology of natural zeolites, vol. 4, Walter de Gruyter GmbH & Co KG, 2018.
  13. Y. T. Tran, J. Lee, P. Kumar, K.-H. Kim and S. S. Lee, "Natural zeolite and its application in concrete composite production," Compos. Part B: Eng., vol. 165, pp. 354-364, 2019, doi: 10.1016/j.compositesb.2018.12.084. DOI:10.1016/j.compositesb.2018.12.084
  14. X.-Y. Wang, "Analysis of hydration-mechanical-durability properties of metakaolin blended concrete," Appl. Sci., p. 1087, 2017. DOI:10.3390/app7101087
  15. T. S. Kim, F. M. Farzad and F. W. Markiv, "Mechanical and durability properties of concretes incorporating natural zeolite," Arch. Civ. Mech. Eng., pp. 554-562, 2016. DOI:10.1016/j.acme.2016.03.013
  16. A. R. Ranjbar, A. Bazyar and S. M. Dousti, "Influence of exposure temperature on chloride diffusion in concretes incorporating silica fume or natural zeolite," Constr. Build. Mater., pp. 393-399, 2013. DOI:10.1016/j.conbuildmat.2013.08.086
  17. Z. F. Jovanović, P. M. Kovačević, T. Čučak and R. Pavlík, "Characterization of cement pastes containing natural zeolite as a pozzolanic admixture," Appl. Mech. Mater., pp. 206-209, 2015. DOI:10.4028/www.scientific.net/AMM.719-720.206
  18. N. A. Hadi and I. A. T. Ahmed, "Sustainable road paving: Enhancing concrete paver blocks with zeolite-enhanced cement," Open Eng., p. 20220581, 2024.
  19. X. Li, K. G. Sun, W. Fang and W. Z. Zheng, "Effect of pozzolanic reaction of zeolite on its internal curing performance in cement-based materials," J. Build. Eng., p. 105503, 2023. DOI:10.1016/j.jobe.2022.105503
  20. M. Kazemian and S. Bazyar, "Internal curing capabilities of natural zeolite to improve the hydration of ultra-high performance concrete," Constr. Build. Mater., p. 127452, 2022. DOI:10.1016/j.conbuildmat.2022.127452
  21. S. W. Qi, W. N. Sun, S. Q. Li and L. Y. Xu, "Effects of natural zeolite replacement on the properties of superhydrophobic mortar," Constr. Build. Mater., p. 128567, 2022. DOI:10.1016/j.conbuildmat.2022.128567
  22. A. M. Mohammadi and M. R. Z. Akbarpour, "Effects of natural zeolite and sulfate ions on the mechanical properties and microstructure of plastic concrete," Front. Struct. Civ. Eng., vol. 16, no. 1, pp. 86-98, 2022. DOI:10.1007/s11709-021-0793-x
  23. A. A. Bazyar and T. H. Zolghadri, "Influence of natural zeolite on fresh properties, compressive strength, flexural strength, abrasion resistance, Cantabro-loss and microstructure of self-consolidating concrete," Constr. Build. Mater., p. 127440, 2022. DOI:10.1016/j.conbuildmat.2022.127440
  24. A. K. Kumar, K. S. Prasad, P. K. Goud, K. S. V. Rao and S. G. Shashanka, "Study on stress strain behavior of concrete with replacement of cement by natural zeolite," J. Eng. Sci., pp. 1679-1685, 2022.
  25. M. V. Mirković, Z. D. Savić, A. Aškrabić and S. B. Aškrabić, "Effects of natural zeolite addition on the properties of lime putty-based rendering mortars," Constr. Build. Mater., p. 121363, 2021. DOI:10.1016/j.conbuildmat.2020.121363
  26. M. Pavlíková, A. Kapicová, A. Pivák, M. Záleská, M. Lojka, O. Jankovský and Z. Pavlík, "Zeolite lightweight repair renders: Effect of binder type on properties and salt crystallization resistance," Mater., vol. 14, no. 13, p. 3760, 2021, doi: 10.3390/ma14133760. DOI:10.3390/ma14133760
  27. Z. Xuan and J. Z. Xuan, "Influence of zeolite addition on mechanical performance and shrinkage of high strength Engineered Cementitious Composites," J. Build. Eng., p. 102124, 2021. DOI:10.1016/j.jobe.2020.102124
  28. G. Kaplan, U. Coskan, A. Benli, O. Y. Bayraktar and A. B. Kucukbaltaci, "The impact of natural and calcined zeolites on the mechanical and durability characteristics of glass fiber reinforced cement composites," Constr. Build. Mater., vol. 311, p. 125336, 2021, doi: 10.1016/j.conbuildmat.2021.125336. DOI:10.1016/j.conbuildmat.2021.125336
  29. S. S. Hashemi and E. Z. F. Ganji, "Laboratory investigation on abrasion resistance and mechanical properties of concretes containing zeolite powder and polyamide tire cord waste as fiber," Constr. Build. Mater., p. 125053, 2021. DOI:10.1016/j.conbuildmat.2021.125053
  30. X. Zhang, J. D. Xu, X. C. Huang and Z. J. Zheng, "Frost resistance of internal curing concrete with calcined natural zeolite particles," Constr. Build. Mater., p. 123062, 2021. DOI:10.1016/j.conbuildmat.2021.123062
  31. Ž. A. Skuodis, K. M. F. Černiauskas, A. D. Kvedaras, I. R. Skuodis, G. Rudžionis and N. A. Rudžionis, "Natural zeolite powder in cementitious composites and its application as heavy metal absorbents," J. Build. Eng., p. 103085, 2021. DOI:10.1016/j.jobe.2021.103085
  32. M. Pekgöz and T. İ. Pekgöz, "Microstructural investigation and strength properties of structural lightweight concrete produced with zeolitic tuff aggregate," J. Build. Eng., p. 102863, 2021. DOI:10.1016/j.jobe.2021.102863
  33. M. Şahmaran, "The effect of replacement rate and fineness of natural zeolite on the rheological properties of cement-based grouts," Can. J. Civ. Eng., pp. 796-806, 2008. DOI:10.1139/L08-039
  34. M. A. Moghadam and I. R. A. Moghadam, "Effects of zeolite and silica fume substitution on the microstructure and mechanical properties of mortar at high temperatures," Constr. Build. Mater., p. 119206, 2020. DOI:10.1016/j.conbuildmat.2020.119206
  35. N. C. Thang, N. V. Y. Khoa, H. P. Q. and T. T. Thang, "Effect of zeolite on shrinkage and crack resistance of high-performance cement-based concrete," Mater., vol. 13, no. 16, p. 3773, 2020, doi: 10.3390/ma13163773. DOI:10.3390/ma13173773
  36. Q. Zhang, J. Chen and H. J. C. M. Wang, "Zeolite to improve strength-shrinkage performance of high-strength engineered cementitious composite," Constr. Build. Mater., vol. 260, p. 117335, 2020, doi: 10.1016/j.conbuildmat.2020.117335. DOI:10.1016/j.conbuildmat.2019.117335
  37. A. D. Egorova and F. K. Egorova, "Ultra-disperse modifying zeolite-based additive for gypsum concretes," in IOP Conf. Ser.: Mater. Sci. Eng., vol. 687, no. 2, p. 022030, 2019. DOI:10.1088/1757-899X/687/2/022030
  38. W. C. Jiang, J. W. Jin, J. Z. Bai, Y. X. Xie and R. J. Xu, "Evaluation of inherent factors on flowability, cohesiveness and strength of cementitious mortar in presence of zeolite powder," Constr. Build. Mater., pp. 61-73, 2019. DOI:10.1016/j.conbuildmat.2019.04.115
  39. Y. Y. Guo and D. S. G. Lv, "Investigation on the potential utilization of zeolite as an internal curing agent for autogenous shrinkage mitigation and the effect of modification," Constr. Build. Mater., pp. 669-676, 2019. DOI:10.1016/j.conbuildmat.2018.12.001
  40. M. J. Aghaei, A. S. Shafigh and K. A. Khoshroo, "Effect of chloride treatment curing condition on the mechanical properties and durability of concrete containing zeolite and micro-nano-bubble water," Constr. Build. Mater., pp. 417-427, 2018. DOI:10.1016/j.conbuildmat.2018.05.086
  41. B. B. Raggiotti, M. J. Positieri, and Á. Oshiro, "Natural zeolite, a pozzolan for structural concrete," Procedia Struct. Integr., vol. 13, pp. 36-43, 2018. DOI:10.1016/j.prostr.2018.11.006
  42. E. Mohseni, W. Tang, and H. Cui, "Chloride diffusion and acid resistance of concrete containing zeolite and tuff as partial replacements of cement and sand," Materials, vol. 10, no. 4, p. 372, 2017. DOI:10.3390/ma10040372
  43. G. Girskas, "Zeolite influence of vibropressing concrete durability," Mater. Sci. Forum, vol. 908, pp. 71-75, 2017. DOI:10.4028/www.scientific.net/MSF.908.71
  44. K. Samimi, S. Kamali-Bernard, A. A. Maghsoudi, M. Maghsoudi, and H. Siad, "Influence of pumice and zeolite on compressive strength, transport properties and resistance to chloride penetration of high strength self-compacting concretes," Constr. Build. Mater., vol. 151, pp. 292-311, 2017. DOI:10.1016/j.conbuildmat.2017.06.071
  45. J. Zhang, Q. Wang, and J. Zhang, "Shrinkage of internal cured high strength engineered cementitious composite with pre-wetted sand-like zeolite," Constr. Build. Mater., vol. 134, pp. 664-672, 2017. DOI:10.1016/j.conbuildmat.2016.12.182
  46. G. Girskas and G. Skripkiūnas, "The effect of synthetic zeolite on hardened cement paste microstructure and freeze-thaw durability of concrete," Constr. Build. Mater., vol. 142, pp. 117-127, 2017. DOI:10.1016/j.conbuildmat.2017.03.056
  47. M. Hirata and I. Jimbo, "Utilization of concrete waste to capture CO₂ with zeolite," Proc. Sch. Eng. Tokai Univ., vol. 41, pp. 9-13, 2016.
  48. G. Girskas, G. Skripkiūnas, G. Šahmenko, and A. Korjakins, "Durability of concrete containing synthetic zeolite from aluminum fluoride production waste as a supplementary cementitious material," Constr. Build. Mater., vol. 117, pp. 99-106, 2016. DOI:10.1016/j.conbuildmat.2016.04.155
  49. S. Seraj, R. D. Ferron, and M. C. G. Juenger, "Calcining natural zeolites to improve their effect on cementitious mixture workability," Cem. Concr. Res., vol. 85, pp. 102-110, 2016. DOI:10.1016/j.cemconres.2016.04.002
  50. D. Nagrockienė and G. Girskas, "Research into the properties of concrete modified with natural zeolite addition," Constr. Build. Mater., vol. 113, pp. 964-969, 2016. DOI:10.1016/j.conbuildmat.2016.03.133
  51. E. Vejmelková, D. Koňáková, T. Kulovaná, M. Keppert, J. Žumár, P. Rovnaníková, Z. Keršner, M. Sedlmajer, and R. Černý, "Engineering properties of concrete containing natural zeolite as supplementary cementitious material: Strength, toughness, durability, and hygrothermal performance," Cem. Concr. Compos., vol. 55, pp. 259-267, 2015. DOI:10.1016/j.cemconcomp.2014.09.013
  52. H. Eskandari, M. Vaghefi, and K. Kowsari, "Investigation of mechanical and durability properties of concrete influenced by hybrid nano silica and micro zeolite," Procedia Mater. Sci., vol. 11, pp. 594-599, 2015. DOI:10.1016/j.mspro.2015.11.084
  53. M. Sedlmajer, A. Hubáček, and P. Rovnaníková, "Properties of concretes with admixture of natural zeolite," Adv. Mater. Res., vol. 1000, pp. 106-109, 2014. DOI:10.4028/www.scientific.net/AMR.1000.106
  54. M. M. Ranjbar, R. Madandoust, S. Y. Mousavi, and S. Yosefi, "Effects of natural zeolite on the fresh and hardened properties of self-compacted concrete," Constr. Build. Mater., vol. 47, pp. 806-813, 2013. DOI:10.1016/j.conbuildmat.2013.05.097
  55. B. W. Jo, C. J. Song, Y. K. Kim, W. Choi, and J. H. Park, "Material characteristics of zeolite cement mortar," Constr. Build. Mater., vol. 36, pp. 1059-1065, 2012. DOI:10.1016/j.conbuildmat.2012.07.020
  56. C. Karakurt and H. Topçu, "Utilization of natural zeolite in aerated concrete production," Cem. Concr. Compos., vol. 32, no. 1, pp. 1-8, 2010. DOI:10.1016/j.cemconcomp.2009.10.002
  57. B. Ikotun and E. S. Olatunbosun, "Strength and durability effect of modified zeolite additive on concrete properties," Constr. Build. Mater., vol. 24, no. 5, pp. 749-757, 2010. DOI:10.1016/j.conbuildmat.2009.11.011
  58. X. Wang and J. Zhang, "Variation in mineral composition by hydration and carbonation in calcium hydroxide matrix containing zeolite," J. Build. Eng., vol. 57, p. 104491, 2022. DOI:10.1016/j.jobe.2022.104491
  59. B. Ahmadi and S. M. Shekarchi, "Use of natural zeolite as a supplementary cementitious material," Cem. Concr. Compos., vol. 32, no. 2, pp. 134-141, 2010. DOI:10.1016/j.cemconcomp.2009.11.005
  60. Y. Tazawa, K. Aoyagi, E. Kasai, and F. N. Kasai, "Admixtures in terms of characterization and properties of mortars," Spec. Publ., vol. 132, pp. 615-634, 1992.
  61. M. A. Shekarchi and N. M. Bahrami, "Use of natural zeolite as pozzolanic material in cement and concrete composites," in Handbook of Natural Zeolites, V. J. Inglezakis and A. A. Zorpas, Eds., Bentham Science, 2012, pp. 665-694. DOI:10.2174/978160805261511201010665
  62. J. Zhang, D. Xu, W. Qi, and X. Zhang, "Effective solution for low shrinkage and low permeability of normal strength concrete using calcined zeolite particles," Constr. Build. Mater., vol. 160, pp. 57-65, 2018. DOI: 10.1016/j.conbuildmat.2017.11.065
  63. M. S. Najimi, J. A. Behfarnia, and B. Sobhani, "An experimental study on durability properties of concrete containing zeolite as a highly reactive natural pozzolan," Constr. Build. Mater., vol. 35, pp. 1023-1033, 2012. DOI:10.1016/j.conbuildmat.2012.04.030
  64. C. C. Ban and K. C. Wong, "Durability properties of ternary blended flowable high performance concrete containing ground granulated blast furnace slag and pulverized fuel ash," J. Teknol., vol. 81, no. 4, pp. 1-8, 2019. DOI:10.11113/jt.v81.13205
  65. A. A. Ghafoori, N. I. M. Mirmohseni, and M. F. Ramezanianpour, "Influence of various amounts of limestone powder on performance of Portland limestone cement concretes," Cem. Concr. Compos., vol. 31, no. 10, pp. 715-720, 2009. DOI:10.1016/j.cemconcomp.2009.07.002
  66. P. Sadeghi, S. Fattahi, and A. G. Mohsen Zadeh, "Mechanical and durability properties of concrete containing zeolite mixed with metakaolin and micro-nano bubbles of water," Struct. Concr., vol. 20, no. 2, pp. 786-797, 2019. DOI:10.1002/suco.201800030
  67. D. Jana, "A new look to an old pozzolan, clinoptilolite-a promising pozzolan in concrete," in Proc. 29th Conf. Cement Microscopy, pp. 168-206, 2007.
  68. I. Kováčik, L. Uhlár, and D. M. Janotka, "Properties and utilization of zeolite-blended Portland cements," Clays Clay Miner., vol. 51, no. 5, pp. 616-624, 2003. DOI:10.1346/CCMN.2003.0510510
  69. T. Šovljanski, S. Miličević, M. Malešev, and R. V. Milović, "The effects of natural zeolite as fly ash alternative on frost resistance and shrinkage of blended cement mortars," Sustainability, vol. 14, no. 5, p. 2736, 2022. DOI:10.3390/su14052736
  70. V. Hooton and C. D. A. Villarreal, "Better pavements through internal hydration," Concr. Int., vol. 29, no. 2, pp. 32-36, 2007.