×
The submission system is temporarily under maintenance. Please send your manuscripts to
Go to Editorial ManagerHigh-performance polymer nanocomposites utilizing different-sized nanofillers had a lot of interest recently. Due to their distinct structural, and thermal characteristics. Multi-wall carbon nanotubes (MWCNT) and nanoclay (NC) have the most interest among the numerous types of reinforcing as filler elements for a polymer. The formation of hybrid from MWCNT and NC at various loadings (0.5%, 1%, and 2wt%) on the characteristics of epoxy polymer have been assessed in this work. The specimens have been created using solution blending procedures with the addition of solvent ethanol at a ratio of 1:1 for dispersed nanofillers, and then they have been re-mixed with epoxy. Tests like X-Ray diffraction (XRD), and thermal conductivity were used to identify properties of epoxy. According to the test results, the thermal conductivity rise as the filler content rises at 1wt%, then start to decrease after 1wt%. The sample with the hybrid filler loading of 1 wt% produced the best performance. Since hybrid epoxy exhibits the best result of the thermal conductivity 135% over MWNT and NC nanocomposites of 1 wt.% reached 0.3568 W/m.K in the increased thermal conductivity property. By examining the EP nanocomposites XRD pattern. The hybrid of epoxy nanocomposites exhibits all of the NC and MWCNT characteristic peaks. Since interactions between the filler and the epoxy cause a shift in the peak location of 1wt%. Due to the homogeneity of the nanofillers entire epoxy matrix, there may be changes in the intensity or location of the peaks at 1% for 2θ= 20.13°, which corresponds to an interlayer distance of d=0.461nm.
The Mono and binary-mixed oxide catalysts were prepared by precipitation and co-precipitation method and investigated for the photocatalytic decolorization of orange G dye which was used as a pollutant model in this study. The structure of the synthesized catalysts were characterized by the X-ray diffraction (XRD), bonding by fourier transfer infrared (FTIR), morphology by scanning electron microscope (SEM) and reflection using UV-VIS diffuse reflectance spectra. The XRD results revealed that the mono oxide catalysts confirm well the cubic phase of cadmium and cerium oxide and that their mixed oxide catalyst i.e. 50Ce/25Cd show the same characteristic peaks of pure cerium oxide with slight shift to higher wave lengths for two crystalline peaks at 33.15° and 56.15° respectively. The FTIR spectra of 50Ce/25Cd mixed oxide catalyst improved the combination between both pure cadmium and cerium oxide catalyst. The diffuse reflectance showed a blue shift towards lower wave length and that the energy gap was increased with an increase in cerium content. Different reaction variables such as, effect of metal content, pH values, amount of hydrogen peroxide and effect of catalyst amount were studied to estimate their effect on the decolorization efficiency of orange G dye. The maximum catalytic activity achieved was 91% at a solution pH of 2.1, catalyst dosage of 1.5 g/L, 0.15 mL of H2O2 /100 mL of reaction volume and initial dye concentration of 10 mg/L after 60 min of reaction time.
Commercial purity iron powders were produced by using a new hydrometallurgy process. It was found that the most important factor in enhancing the purity of iron was the number of water washing process. X-ray diffraction pattern showed that the high peak purity of iron powder increased with increasing the number of water washing. The developed new methodology was based on the reaction between the aqueous ferrous sulfate and the hydrochloric acid with the presence of high purity aluminum flake. The purity of iron powders increased considerably with increasing the multi-water washing for leachate containing iron powders. The purity of iron powders was reached up to approximately 93.5%. The mean particle size distribution and apparent density for the highest value of purity are 50-100 µm and 2.85 g/cm3 respectively.
The purpose of this study is to investigate the potential of biochar derived from Peganum harmala (Pgh) seeds as an adsorbent material for wastewater treatment. Biochar is a cost-efficient, ecologically friendly, and effective bio-sorbent for a wide range of pollutants in wastewater. Researchers are investigating the production of biochar from novel biomass sources. Phosphoric acid (H3PO4) was utilized in a chemical activation technique to produce biochar at various concentrations (20%, 30%, and 40%). The pyrolysis process lasted three hours at 600°C in a tube furnace with an inert nitrogen gas atmosphere. Elemental analysis, Brunauer-Emmett-Teller (BET) nitrogen adsorption, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), energy dispersive X-ray spectroscopy (EDX), The biochar was characterized using several techniques, including elemental analysis, X-ray diffraction, Fourier transform infrared spectroscopy (FTIR), Brunauer-Emmett-Teller (BET) nitrogen adsorption, scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDX). The findings demonstrate the significant potential of Pgh seed-derived biochar as an inexpensive and ecologically acceptable sorbent material. A large surface area (691.58 m2g−1) was achieved at 600◦C for three hours with 40% H3PO4 activation.
The corrosion behavior of martensite phase in Cu-Al-Be shape memory alloy with aging at 150 at time 2,4and 6 hour and quenching ice water with salt, water at room temperature and oil media study by open circuit potential, tafal polarization and cyclic polarization. The microstructure of martensite study by optical microscope and x-ray diffraction(XRD) and transformation temperature was determined by Di?erential Scanning Calorimeter (DSC).the result show aging martensite at 150 at 2 and 4 hour have high open circuit potential, low corrosion current density , high corrosion potential and pitting potential than martensite without aging.
The Electrodeposition process has been used to prepare Nickel-Tungsten alloys on low carbon steel substrate by using ammonical citrate bath. The influence of deposition condition by variation of current density (0.04-0.2 A/cm2) and solution temperature (60-70 °C), on the microstructure was studied. The optical microscope and the scanning electron microscopy (SEM) were used to study the morphology of the deposit while the energy dispersive spectroscopy (EDS) was used to approximate the composition, in addition to X-Ray diffraction examination. The results show that the current efficiency has the major influence on the tungsten content in the alloys due to the formation of ternary complex which reflected into the properties of the deposit._x000D_ Keywords:
In this research, we successfully obtained Ni/SiC micro-composite coatings with various contents of SiC particles of particle size(10 ?m), by using electrodeposition method from nickel watts bath in which the SiC particles suspend. The effects of the current density, temperature, and particle loading(PL) of SiC particles in the electrolyte on the morphology, texture, and vol% of SiC in deposit were investigated. The morphological and structural analysis show uniform distribution of SiC particles within the composite coatings. It was found that the depositing conditions affect the microstructure of deposited nickel and the SiC vol% in deposit. Furthermore, the vol% of SiC increases in deposit by increasing the particle loading(PL) in the bath, while decreased by increasing the current density. Also the higher values of SiC vol% were obtained at temperature (50°C).
Welding residual stress has influences on fatigue, fracture, and corrosion. It is therefore important to explore the welding factors effect on the residual stresses. In this work, four welding factors (current, arc voltage, welding travel speed and included angle) were used to weld low carbon steel (ASTM A516 Grade 60).The experiments included welding of (60) pieces with dimensions of (300 x 150) mm and 10 mm thickness that were conducted based on the design matrix founded by using design of experiment (DOE) software (DESIGN EXPERT 10) with response surface methodology (RSM) technique. The X-Ray diffraction (XRD) method was used to measure the residual stress, which was then modeled and optimized in terms of the welding factors using (RSM) technique. The data showed that the welding travel speed and arc voltage have a significant influence on the residual stress. It was found that the optimum solution for minimum residual stress was at 450 Amp welding current, 34 volt arc voltage, 38 cpm welding speed, and 60? included angle. Where, the optimum value of residual stress was (-88.4 MPa). Finally, the predicted and experimental results of residual stress were in agreement with a maximum error of 1.8%.
In the present study, magnesium-based composites reinforced with different volume fractions (3, 5, 10, and 15) vol.% of micro sized Al2O3 particulates were fabricated by powder metallurgy technique which involves mixed, compacted and sintered. Powders were mixed by ball milling (without balls) for 6 hours at rotation speed 60 rpm. Then powder was compacted at 550 MPa and sintered at 530?C for 2 hours. Microstructures of sintered composites have been investigated by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX) and X-ray diffraction (XRD) energy dispersive. SEM image of sinter samples exhibit good bonding between the magnesium matrix and the alumina. The microhardness and wear resistance of micro composites has been improved significantly compared to that of pure magnesium. Highest value of microhardness is 97 HV at the volume fraction of 10 vol.% Al2O3.
In this study a Nickel-Titanium-Cupper shape memory alloys was manufactured by powder metallurgy (PM) technique, powder mixture of 50% Ti , 47% Ni and 3% Cu was prepared by mixing for two hours and compacted in a press machine using various compacting pressure (600, 700 and 800) MPa , sample was then sintered for 5 hrs in an electrical tube vacuum furnace using sintering temperature of (850?C, 900?C and 950?C) .phase analysis of samples was conducted by X-ray diffraction test, the effect of different sintering temperature and compacting pressure on the porosity, microhardness ,compression strength and the shape memory effect (SME) was studied, the result showed decrease in the porosity and increasing in the shape recovery ,compression strength and microhardness with increasing compacting pressure and at lower sintering temperature and hence the best results was at 800MPa compacting pressure and 850?C sintering temperature.
In this study the friction stir lap welding was carried out by a new technique (diffusion bonding phenomenon) between (AA1100 and low carbon steel C10 sheets of 3mm and 1mm thickness respectively. These alloys have difference ranges in melting temperature and other physical properties. Different parameters were used: tool rotation speeds (630, 1250) rpm, travel speeds (80, 32) mm/min. and pin length (2.8,3) mm using cylindrical threaded pin. Many tests and inspections were performed such as tensile shear test and X-Ray diffraction tests. Microhardness and microstructure observations were conducted by using optical and SEM. The above tests were used to evaluate the weld quality and joint efficiency under different welding parameters. Best result for FSLW by diffusion phenomenon appear in (low carbon steelC10 / AA1100-H112) joint at 1250rpm in 32 mm/min. with 2.8mm pin length and the maximum tensile shear strength was (3.9)KN.It was found that the highest micro hardness was (138HV) at the interface between the low carbon steel and AA1100.