Vol. 21 No. 3 (2018) Cover Image
Vol. 21 No. 3 (2018)

Published: September 30, 2018

Pages: 320-326

Articles

Chemical Extractive Technique for Commercial Purity Metals

Abstract

Commercial purity iron powders were produced by using a new hydrometallurgy process.  It was found that the most important factor in enhancing the purity of iron was the number of water washing process.  X-ray diffraction pattern showed that the high peak purity of iron powder increased with increasing the number of water washing. The developed new methodology was based on the reaction between the aqueous ferrous sulfate and the hydrochloric acid with the presence of high purity aluminum flake.   The purity of iron powders increased considerably with increasing the multi-water washing for leachate containing iron powders. The purity of iron powders was reached up to approximately 93.5%. The mean particle size distribution and apparent density for the highest value of purity are 50-100 µm and 2.85 g/cm3 respectively.

References

  1. R. Singh, Introduction to basic manufacturing processes and workshop technology, New Age International (P) Limited, Publishers, India, 2006.
  2. S.S. Maklakov, A.N. Lagarkov, S.A. Maklakov, Y.A. Adamovich, D.A. Petrov, K.N. Rozanov, I.A. Ryzhikov, A.Y. Zarubina, K.V. Pokholock, D.S. Filimonov, Corrosion resistive magnetic powder Fe@SiO2 for microwave applications, J of Alloys and Compounds, 706(2017)267-273.
  3. W.B. James, Powder metallurgy methods and applications, ASM Handbook, Powder Metallurgy, Vol. 7, 2015, P. Samal and J. Netwkirt, ASM International.
  4. P. Mariot, M.A. Leeflang, L. Schaeffer, J. Zhou, An investigation on the properties of injection-molded pure iron potentially for biodegradable stent application, Powder Technology, 294(2016)226-235.
  5. J. Capek, D. Vojtech, A. Oborna, Microstructural and mechanical properties of the biodegradable iron foam prepared by powder metallurgy, Materials and Design, 83(2015)468-482.
  6. M. Soori, K. Zarezadeh, S. Sheibani, F. Rashchi, Mechano-chemical processing and characterization of nano-structured FeS powder, Advanced Powder Technology, 27(2016)558-563.
  7. L.C. Backer, E. Esten, C.H. Rubin, S. Kieszk, M. McGeehin, Assessing acute diarrhea from sulfate in drinking water, Journal of the American Water Works Association, 93(2001)76-84.
  8. Z. Wu, D. Ren, H. Zhou, H. Go, J. Li, Sulfate reduction and formation of iron sulfide minerals in nearshore sediments from Qi'ao Island, Pearl River Estuary, South China, Quaternary International, 452(2017)137-147.
  9. Mohapatra M, Anand S. Synthesis and applications of nanostructured iron oxides/hydroxides–a review. International Journal of Engineering, Science, and Technology. 2010;2(8).
  10. Kharisov, Boris I., HV Rasika Dias, Oxana V. Kharissova, Victor Manuel Jiménez-Pérez, Betsabee Olvera Pérez, and Blanca Muñoz Flores. "Iron-containing nanomaterials: synthesis, properties, and environmental applications." RSC Advances 2, no. 25 (2012): 9325-9358.
  11. Stoia M, Tamaş A, Rusu G, Moroşanu J. "Synthesis of Magnetic Iron Oxides from Ferrous Sulfate and Substitutes Amines". Studia Universitatis Babes-Bolyai, Chemia. 2016 Dec 1;61(4).
  12. Ramimoghadam, Donya, Samira Bagheri, and Sharifah Bee Abd Hamid. "Progress in electrochemical synthesis of magnetic iron oxide nanoparticles." Journal of Magnetism and Magnetic Materials 368 (2014): 207-229.
  13. Qin, W., Yang, C., Yi, R. and Gao, G., 2011. Hydrothermal synthesis and characterization of single-crystalline α-Fe 2 O 3 nanocubes. Journal of Nanomaterials, 2011, p.3.
  14. Datta B. K., “Powder Metallurgy: An Advanced Technique of Processing Engineering Materials”. PHI Learning Pvt. Ltd., 2012.
  15. Basim G. B. and Khalili M., “Particle size analysis on wide size distribution powders; effect of sampling and characterization technique. Advanced Powder Technology”, 26 (2015) 200-207.
  16. Eisen W. B., Ferguson B. L., German R. M., Iacocca R., Lee P. W., Madan, D. and Trude Y., “Powder metal technologies and applications”, 1998.
  17. Angelo P. C. and Subramanian R., "Powder metallurgy: science, technology, and applications". PHI Learning Pvt. Ltd, 2008.
  18. Mikell Groover, “Fundamentals OF Modern Manufacturing Materials, Processes and Systems”, John Wiley & Sons Fourth Edition, (2010)347-352.
  19. Koryta Dvorak and Kavan Ladislav, “Principles of electrochemistry”, Chichester (W. Sx) etc.: Wiley, 1993.
  20. Djokic Stojan S., “Electrodeposition: theory and practice (modern aspects of electrochemistry)”, 2010.