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Search Results for epoxy-nanocomposites

Article
Study the Effect of Hybrid Nanofillers Content on the X-ray Diffraction and Thermal Conductivity Properties of Epoxy-Based Nanocomposites

Hajer Alhussiny, Muayad Albozahid

Pages: 286-291

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Abstract

High-performance polymer nanocomposites utilizing different-sized nanofillers had a lot of interest recently. Due to their distinct structural, and thermal characteristics. Multi-wall carbon nanotubes (MWCNT) and nanoclay (NC) have the most interest among the numerous types of reinforcing as filler elements for a polymer. The formation of hybrid from MWCNT and NC at various loadings (0.5%, 1%, and 2wt%) on the characteristics of epoxy polymer have been assessed in this work. The specimens have been created using solution blending procedures with the addition of solvent ethanol at a ratio of 1:1 for dispersed nanofillers, and then they have been re-mixed with epoxy. Tests like X-Ray diffraction (XRD), and thermal conductivity were used to identify properties of epoxy. According to the test results, the thermal conductivity rise as the filler content rises at 1wt%, then start to decrease after 1wt%. The sample with the hybrid filler loading of 1 wt% produced the best performance. Since hybrid epoxy exhibits the best result of the thermal conductivity 135% over MWNT and NC nanocomposites of 1 wt.% reached 0.3568 W/m.K in the increased thermal conductivity property. By examining the EP nanocomposites XRD pattern. The hybrid of epoxy nanocomposites exhibits all of the NC and MWCNT characteristic peaks. Since interactions between the filler and the epoxy cause a shift in the peak location of 1wt%. Due to the homogeneity of the nanofillers entire epoxy matrix, there may be changes in the intensity or location of the peaks at 1% for 2θ= 20.13°, which corresponds to an interlayer distance of d=0.461nm.

Article
Synergistic Effects of Hybrid Nano-Calcium Carbonate and Nano-Talc Fillers on the Electrical, Thermal, and Morphological Properties of Epoxy-Glass Fiber Composites

Nishant Bhore, Prashant Thorat, Mangesh Deshmukh

Pages: 319-326

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Abstract

This research investigates the influence of single and hybrid mineral nanofillers on the morphological, thermal, and electrical properties of epoxy-based glass fiber composites. Nanocomposites were fabricated using hand lay-up technique, incorporating nano-calcium carbonate (CaCO₃) and nano-talc with particle size of 50 to 100 nm into an epoxy matrix with 5-ply E-glass/S-glass fiber. The study evaluates composites with 2-8 wt% of nano-CaCO₃, and hybrid systems containing nano-CaCO₃ (2-8 wt%) and nano-talc (1-4 wt%). Morphological analysis via Scanning Electron Microscopy (SEM) assessed nanofiller dispersion, while thermal properties were analyzed using Differential Scanning Calorimetry (DSC) for glass transition temperature (Tg). Electrical performance was evaluated through dielectric breakdown voltage (ASTM D149) and surface resistivity (ASTM D257). SEM analysis showed filler dispersion depended on concentration, with optimal distribution at 4-6 wt% before significant agglomeration at higher concentrations. DSC results revealed increased Tg with nanofillers, peaking for the composite with 6 wt% CaCO₃ and 3 wt% talc, indicating enhanced thermal stability. The dielectric breakdown voltage peaked at 17.6 kV for 2 wt% CaCO₃ and 1 wt% talc composite, while surface resistivity was highest for 4 wt% CaCO₃ and 2 wt% talc (73.74×1012Ω). All formulations maintained UL 94 V-1 flammability rating. The study concludes that the synergistic interaction between nano-CaCO₃ and nano-talc enables significant tailoring of thermal and electrical properties for advanced applications.

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