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Go to Editorial ManagerDistillation columns are among the most critical units in chemical processes, especially in oil refineries. This research aims to develop a mathematical model for a nonlinear multicomponent naphtha distillation column using real experimental data. The naphtha distillation column used in this research consists of a column with a diameter of 2.2 m and a height of 16.6 m, containing 20 trays of type (valve tray). The process currently operates in Al-Dora Refinery as part of the Midland Refinery Company in eastern Baghdad, Iraq. Four manipulated variables (reflux flow rate, reboiler heat duty, light compound fraction in the feed, and feed flow rate) were tested for their impact on four control variables (light compound fraction in the top product, light compound fraction in the bottom product, amount of top product, and amount of bottom product). A 4x4 transfer function is produced by representing the obtained dynamic models for the variables under study using various second-order models (having different damping factors) with dead time.
This work investigated the removal of the reactive green (R.G) dye from wastewater using the photo-Fenton process. Batch experiments were carried out to research the role of the Impacts of operating parameters. The dosage of H2O2; dosage Fe+2; pH; temperature, and irradiation time were examined. Maximum decolorization efficiencies green dye were achieved at the [H2O2]=100 ppm; [Fe2+]=20 ppm; pH 3; temperature=56 °C and irradiation time=90 min. This research focuses on modeling, kinetics and thermodynamics of the removal of pollutant (reactive green dye) of water. The results showed that the decolorization kinetic of R.G followed pseudo-first-order reaction kinetic. Also the thermodynamic parameters ?G?, ?H? and ?S? were determined using the Van't Hoff equation for the oxidation processes. The changes in Gibbs free energy showed the oxidation process under normal conditions is non-spontaneous.