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Go to Editorial ManagerThe adsorption characteristics of Nickel (II) onto Iraqi Bentonite clay from aqueous solution have been investigated with respect to changes in pH of solution, adsorbent dosage, contact time and temperature of the solution. The maximum removal efficiency of Nickel (II) ions is 96% at pH=6.5 and exposure to 100 g/L adsorbent. For the adsorption of Nickel (II) ions, the Freundlich isotherm model fitted the equilibrium data better than the Langmuir isotherm model. Experimental data are also evaluated in terms of kinetic characteristics of adsorption and it was found that the adsorption process for Ni+2 ions follows well pseudo-second-order kinetics. Thermodynamic functions, the change of free energy (?G°), enthalpy (?H°) and entropy (?S°) of adsorption are also calculated for Nickel (II) ions. The results show that the adsorption of the Nickel (II) ions on Iraqi Bentonite is feasible and exothermic at (20-50) °C.
Platinum, copper, and nickel were founded the best metals used in resistance temperature detectors RTDs. They commonly used in laboratory and industrial applications because they provide accurate and reliable measurements in a wide temperature range from (- 200 to 850 °C). They have high conductivity, sensitivity, and hardness to resist strain shock, pressure, and vibration. The accuracy level of them depends on reliability, stability, repeatability, linearity, and response to time. This study aims to determine and compare the accuracy of these three metals in regarding to their features which include stability, repeatability, and response time. The study has gathered and analyzed the data of these suitable and precise metals and compared with each other. The results showed that platinum is widely needed for RTDs due to its precision, stability, higher accuracy, and linearity output, while copper and nickel are not stable or repeatable as platinum. It was indicated that temperature coefficient of resistance TCR for nickel is bigger and for copper is medium, but for platinum is lower.
Galvanic corrosion of Nickel-Chrome alloy (Ni-Cr alloy) and Copper (Cu) coupled in 5% sulfuric acid solution was investigated. The effects of agitation velocity, temperature, and time on the galvanic corrosion current and the weight loss of both metals in both free corrosion and galvanic corrosion were investigated. The trends of open circuit potential (OCP) of each metal and galvanic potential (Eg) of the couple were also determined. The results showed that Cu was cathodic relative to Ni-Cr alloy in galvanic couple and the corrosion potential of the couple (Ni- Cr alloy /Cu) was between the values of the two single components because the OCP of copper shifted to positive with the increase in velocity. Under stagnant conditions initially the galvanic current was more negative then shifted to the positive with time. The corrosion of Ni-Cr alloy decreased with time because the passivation layer was formed on the surface. Under flow conditions, the galvanic current sharply shifted to the negative direction (increase galvanic current from Ni-Cr alloy (anode) to Cu (cathode) during the first few minutes.
The heavy metals are considered dangerous pollutants which harm health and environment. The adsorption process is the cost effective process to get-rid of heavy metal efficiently. In this study, the adsorption bed of Nickel is simulated by using COMSOL Multiphysics to find the effect of different operating parameters namely; flow rate, temperature and pollutant concentration on adsorption bed efficiency. The modeling of non-isothermal adsorption bed based on experimental isotherms kinetic of previous work is developed too. The results showed that the optimal conditions to generate maximum removal efficiency of heavy metal were at 50?C inlet temperature, 0.1 M inlet concentration, and 80 ml/min flow rate to achieve removal values higher than 50 % of long operation period time.
In this research, we successfully obtained Ni/SiC micro-composite coatings with various contents of SiC particles of particle size(10 ?m), by using electrodeposition method from nickel watts bath in which the SiC particles suspend. The effects of the current density, temperature, and particle loading(PL) of SiC particles in the electrolyte on the morphology, texture, and vol% of SiC in deposit were investigated. The morphological and structural analysis show uniform distribution of SiC particles within the composite coatings. It was found that the depositing conditions affect the microstructure of deposited nickel and the SiC vol% in deposit. Furthermore, the vol% of SiC increases in deposit by increasing the particle loading(PL) in the bath, while decreased by increasing the current density. Also the higher values of SiC vol% were obtained at temperature (50°C).
The presence of heavy metal pollutants in refinery effluent significantly impacts the corrosion rate of carbon steel. The focus of this research is to analyze the impact of various inorganic pollutants, including copper, vanadium, nickel, and chromium ions, on the corrosion of carbon steel across different solutions. After conducting a thorough examination of various operating conditions, including pollutant concentration (ranging from 300-3000 ppm), temperature (30-60? C), and flow velocity (0-800 rpm). Our research shows that copper ions have the highest corrosion rate, with vanadium ions being a close second. Conversely, nickel and chromium had the most negligible impact on corrosion rate and, in some instances, even exhibited corrosion inhibition effects. It was also observed that an increase in flow velocity and temperature significantly amplified the corrosion rate of the metal ions investigated.
The Electrodeposition process has been used to prepare Nickel-Tungsten alloys on low carbon steel substrate by using ammonical citrate bath. The influence of deposition condition by variation of current density (0.04-0.2 A/cm2) and solution temperature (60-70 °C), on the microstructure was studied. The optical microscope and the scanning electron microscopy (SEM) were used to study the morphology of the deposit while the energy dispersive spectroscopy (EDS) was used to approximate the composition, in addition to X-Ray diffraction examination. The results show that the current efficiency has the major influence on the tungsten content in the alloys due to the formation of ternary complex which reflected into the properties of the deposit._x000D_ Keywords:
In this study a Nickel-Titanium-Cupper shape memory alloys was manufactured by powder metallurgy (PM) technique, powder mixture of 50% Ti , 47% Ni and 3% Cu was prepared by mixing for two hours and compacted in a press machine using various compacting pressure (600, 700 and 800) MPa , sample was then sintered for 5 hrs in an electrical tube vacuum furnace using sintering temperature of (850?C, 900?C and 950?C) .phase analysis of samples was conducted by X-ray diffraction test, the effect of different sintering temperature and compacting pressure on the porosity, microhardness ,compression strength and the shape memory effect (SME) was studied, the result showed decrease in the porosity and increasing in the shape recovery ,compression strength and microhardness with increasing compacting pressure and at lower sintering temperature and hence the best results was at 800MPa compacting pressure and 850?C sintering temperature.