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Search Results for heavy-metals

Article
Single and Binary Biosorption isotherms of Different Heavy Metal Ions Using Fungal Waste Biomass

Hasanain Saad Al-Hares

Pages: 673-684

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Abstract

The ability of fungal waste biomass type White Agaricus Bisporus to biosorb Pb(II) ,Cr(III), Cd(II) and Co(II) from wastewater was investigated in batch process. Single and binary mixtures were used at low metal concentration wastewater treatment. The size of the biosorbent ranged 0.3-1 mm. The biosorption capacity of the biosorbent was evaluated under equilibrium conditions at 25 °C. Results indicated that the biosorption capacity of waste of fungi for the binary mixture was always lower than that for a single component system. Eight isotherm models were used to fit the experimental data of single system and Langmuir model was found a suitable to describe the biosorption data. The maximum uptake capacity (qe) of Pb(II), Cr(III), Cd(II) and Co(II) in single system was 158.73, 46.94, 40.16 and15.94 mg/g respectively with correlation coefficients 0.999,0.998,0.988 and 0.991 respectively. For binary system, four biosorption models were used to fit the experimental data. Extended Langmuir model gave the best fitting. The removal percentage of heavy metals onto fungal waste biomass was in order of Pb(II) > Cr(III) > Cd(II) > Co(II) in both single and binary system. The results show that the using waste of fungi as a biosorbent of heavy metals gave a higher uptake capacity of four heavy metals.

Article
Comparison between Performance of Okra Waste and Wheat Bran for Removing some Heavy Metals from Wastewater

Karim Khalifa Esgair

Pages: 36-44

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Abstract

In the present work, the  agricultural wastes which are wheat bran and raw okra waste used  as adsorbent material for adsorption  of cadmium and copper ions from wastewater .The effect of adsorption variable which include initial  pH of solution , agitation speed, agitation time, initial concentration of cadmium and copper ions, and amount of adsorbent material were investigated  in a batch process in order to obtain the  maximum  ions removal from wastewater .The results obtained from experimental investigation show that the percentage removal   of metal ions  increases with increasing pH and agitation speed until a maximize value after that it decreased with increasing pH and agitation speed. Also increases with increasing amount of adsorbent material and agitation time until a maximize value then reach a constant value   approximately , and decreasing with increasing  metal ions concentration .The maximum removal percent of cadmium and copper ions were  85.8%  and 52.7 % respectively which obtained at pH equal 5.0, agitation speed 150 revolution per minute, agitation  time 105 minute , metal ion concentration 40mg /L ,and adsorbent amount 1.5gm when using wheat bran as adsorbent material ,while obtained  the maximum removal percent of cadmium and copper ions were  81.7%  and 47.8 % which obtained at pH equal 6.0, and pH equal 5.0 respectively , agitation speed 150 revolution per minute, agitation  time 90 minute ,metal ion concentration 40 mg /L ,and adsorbent amount 1.5gm when using okra waste as adsorbent material. From above result the wheat bran and okra waste was a best adsorbent material for removal cadmium and copper ions from wastewater but wheat bran slightly more effective than okra waste._x000D_  

Article
Studying the Effect of Operating Parameters on the Removal of Nickel Ion from an Adsorber by Using COMSOL Multiphysics Simulation

Mustafa M Hathal, Basim O Hasan

Pages: 357-364

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Abstract

The heavy metals are considered dangerous pollutants which harm health and environment. The adsorption process is the cost effective process to get-rid of heavy metal efficiently.  In this study, the adsorption bed of Nickel is simulated by using COMSOL Multiphysics to find the effect of different operating parameters namely; flow rate, temperature and pollutant concentration on adsorption bed efficiency.  The modeling of non-isothermal adsorption bed based on experimental isotherms kinetic of previous work is developed too. The results showed that the optimal conditions to generate maximum removal efficiency of heavy metal were at 50?C inlet temperature, 0.1 M inlet concentration, and 80 ml/min flow rate to achieve removal values higher than 50 % of long operation period time.

Article
The effect of different heavy metals pollutants in refinery effluent on corrosion rate of carbon steel

Sahir M. Al-Zuraiji, Basim O. Hasan, Ola M. Abdulwaheed

Pages: 320-325

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Abstract

The presence of heavy metal pollutants in refinery effluent significantly impacts the corrosion rate of carbon steel. The focus of this research is to analyze the impact of various inorganic pollutants, including copper, vanadium, nickel, and chromium ions, on the corrosion of carbon steel across different solutions. After conducting a thorough examination of various operating conditions, including pollutant concentration (ranging from 300-3000 ppm), temperature (30-60? C), and flow velocity (0-800 rpm). Our research shows that copper ions have the highest corrosion rate, with vanadium ions being a close second. Conversely, nickel and chromium had the most negligible impact on corrosion rate and, in some instances, even exhibited corrosion inhibition effects. It was also observed that an increase in flow velocity and temperature significantly amplified the corrosion rate of the metal ions investigated.

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