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Go to Editorial ManagerThe electrodes material plays an important role in the amount of electricity produced in microbial fuel cells (MFCs). Metal electrodes used in MFCs are subject to biological and concentration cell corrosion which leads to a decrease in the cell efficiency. In the present work, the corrosion behavior of three selected electrode materials, namely, stainless steel, copper, and zinc under different operating conditions was investigated and discussed. In anode chamber, the microorganism (MO) used was Saccharomyces cerevisiae (yeast) with sodium acetate as a substrate forming the microbial corrosive solution. In the cathode chamber, the corrosive solution is aerated water. The effects of different operating parameters on the corrosion rate (CR) of these electrodes were studied such as: microorganism concentration, aeration of cathode chamber, and flow velocity in cathode chamber. The potential of the each electrode was measured to understand the corrosion behavior of electrodes and the produced current was also investigated. It was found that the corrosion rate of the electrodes in both anode and cathode chambers increases with increasing MO concentration in anode chamber and with increasing agitation speed in cathode chamber. The bio-corrosion is an important part of the corrosion occurring in microorganism chamber. The stainless steel exhibited the lowest corrosion rate for the whole investigated range of operating parameters followed by copper. The zinc electrode was found to be poor as an electrode in MFC as its corrosion rate was very high in all conditions investigated. In addition, this study showed that the air pumping in water chamber causes an appreciable increase in the corrosion rate in both chambers and an increase in the produced current.
In the present work the effect of Corrosion & Scale Inhibitor was evaluated by using of the commercial product (Kurita S2050) that mainly containing of (Na2HPO4) sodium phosphate as corrosion inhibitor and (C6H11NaO7) sodium glocunate as scale inhibitor & dispersant. The dosing rate of this chemical was controlled according to the treatment system depend mainly on the monitoring of LI & RI indexes for (30) days treatment in the cooling tower unit of Al-Dora Oil refinery-Baghdad. The corrosion rate and the corrosion inhibitors efficiency were calculated by measurement of weight loss in standard test coupon (AISI 1010). After 30 day of the Field Test, the result show that the treatment program performance was effective in the corrosion & scale inhibition through an acceptable corrosion rate less than 0.018 in gmd. Also the result of corrosion rate was analyzed statistically by using of (ANN) to formulate a prediction equation to corrosion rate identification.
The impact of flow velocity (0-900 rpm) on the corrosion rate of carbon steel in a wide range of sulfuric acid concentrations (0-90% in H2O) at 30 °C and 1 h was studied and discussed. In addition, the efficiency of corrosion inhibitor (dimethyl disulfide, DMD) was evaluated in hardest corrosion conditions for the range of velocity investigated. The results revealed that increasing the flow velocity of H2SO4 solution, increases the corrosion rate depending on the acid concentration. When the flow velocity is increased of H2SO4 solution, the corrosion potential was shifted to more negative. The DMD inhibitors showed significant inhibition efficiency at high velocities, where the highest percentage of inhibitor efficiency reached 98% at 900 rpm.
The presence of heavy metal pollutants in refinery effluent significantly impacts the corrosion rate of carbon steel. The focus of this research is to analyze the impact of various inorganic pollutants, including copper, vanadium, nickel, and chromium ions, on the corrosion of carbon steel across different solutions. After conducting a thorough examination of various operating conditions, including pollutant concentration (ranging from 300-3000 ppm), temperature (30-60? C), and flow velocity (0-800 rpm). Our research shows that copper ions have the highest corrosion rate, with vanadium ions being a close second. Conversely, nickel and chromium had the most negligible impact on corrosion rate and, in some instances, even exhibited corrosion inhibition effects. It was also observed that an increase in flow velocity and temperature significantly amplified the corrosion rate of the metal ions investigated.
In this paper, the efficiency of six different types of corrosion inhibitors used in Basrah drinking water tanks was assessed using a potentiostatic test method. The mechanism of adsorption of silicate and phosphate inhibitors in AISI 316 stainless steel surfaces and the effects of different water components in inhibitors are discussed in detail. The values of corrosion rate obtained from the Potentiostatic test showed that the protection against corrosion in the presence of inhibitors is better compared to the case of absence of inhibitors. The results of the six types of corrosion inhibitors tested showed that the inhibitory efficacy is higher below the temperatures 45oC, but when raise the temperature above 45oC the inhibitory efficiency becomes to decrease. Also, the test results indicated that the corrosion inhibitor involves silicate products provided more inhibited efficiency compared to the phosphate inhibitor alone or used the combined silicate/phosphate corrosion inhibitor. The inspection of the surface of the tested samples using optical methods shows that the pitting corrosion is demonstrated on the specimen surfaces after testing with or without inhibitors.
The aim of this work is to investigate the effect of soil corrosion on the critical buckling load of circular columns made of 2014-T4 aluminum alloy. In this work, 24 specimens were used and buried in the soil for 120 days. The samples divided into two groups (12 columns with corrosion before shot penning (SP) and ultrasonic impact treatment (UIT), and 12 columns with corrosion after combined surface treatments (SP+UIT)). The experimental1results revealed1that the corrosion negatively1affects the mechanical properties1of the material, and the1reduction percentage (R%) for1ultimate tensile strength (UTS) and1yield strength (YS) was (1.95% and 4.57%) respectively. After combined surface treatments (SP+UIT) for the corroded columns, the ultimate1tensile strength (UTS) and yield1strength (YS) were improved with (2.42%, and 2.87%) respectively. Perry-Robertson, Rankine, and ANSYS were used to estimate the critical buckling load (Pcr) and compare it with the experimental results. Rankine and Perry's formulas have been achieved a good agreement with the experimental without and with (1.5) factor of safety respectively. While ANSYS gave satisfactory prediction with a safety factor of (2.2, and 2.7) and (1.9, and 2.7) for long and intermediate columns before and after (SP+UIP) respectively.
The separation of water from crude oil emulsions is a critical and complex challenge in petroleum production and processing. Water-in-oil (W/O) emulsions increase viscosity, pose corrosion risks, reduce refining efficiency, and raise significant environmental concerns. Traditional separation methods often struggle with stable emulsions containing small droplets due to limitations in cost, environmental impact, and effectiveness. Electro-coalescence demulsification has emerged as a promising technique that applies electric fields to enhance droplet coalescence, facilitating efficient water removal. This comprehensive review examines the influence of electrode geometry on electro-coalescence systems in depth, synthesizes key findings from numerous studies, and provides a detailed analysis of electrode spacing calculations, critical conditions for effective demulsification, and optimal operational parameters. By exploring these aspects comprehensively, the review offers insights into how electrode design affects demulsification efficiency, guiding future advancements in crude oil processing and contributing to more sustainable practices in the petroleum industry.
Super-hydrophobic is the tendency of a surface to spit out water droplets. Only a surface with high apparent contact angle (>1500), low contact angle hysteresis (<100), low sliding angle (<50), and strong Cassie model state stability is considered a super-hydrophobic surface. In an attempt to create highly hydrophobic synthetic surfaces suitable for a range of uses, attempts have been made to mimic the super-hydrophobicity found in natural materials (such as lotus leaves). Due to its wide range of applications including waterproof, anti-fog, anti-ice and anti-corrosion surface, the laser processing process achieved the use of process parameters which had a significant impact on the roughness factor. High roughness factor F. At constant values of p = 3 mW and ω = 10 μm, at scanning speeds of 6000 mm/s.