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Go to Editorial ManagerIn this work, model fuel (Thiophene in hexane) was treated for sulfur removal by adsorptive desulfurization method using modified bentonite with sodium (Na-B) adsorbent. Batch and continuous mode were used in this study. Several operating parameters such as initial thiophene concentration of 250 to 2000 mg/L , adsorbent dose 0.1 to 0.8g/ml were studied for sulfur removal %. Also a comparison between raw and modified bentonite was performed in this study. In continuous mode, a packed bed of Na-B adsorbent column was used at constant initial thiophene concentration and liquid hourly space velocity (LHSV) to study the breakthrough curve of thiophene. The results showed that Na-B adsorbent was better than raw bentonite in removal of sulfur components. The removal percentages was 67,75,87,and 91% for 500 mg/L initial thiophene concentration using adsorbent dose o.1, 0.2, 0.4 and 0.8g/ml respectively , and 87, 75, 57, and 53% for adsorbent dose of 0.2 g/ml using initial thiophene concentration of 250, 500, 1000, and 2000 mg/L respectively. It was concluded that when increase the dose of adsorbent, the removal of sulfur increase , and when increase the initial concentration the removal decrease.
The adsorption characteristics of Nickel (II) onto Iraqi Bentonite clay from aqueous solution have been investigated with respect to changes in pH of solution, adsorbent dosage, contact time and temperature of the solution. The maximum removal efficiency of Nickel (II) ions is 96% at pH=6.5 and exposure to 100 g/L adsorbent. For the adsorption of Nickel (II) ions, the Freundlich isotherm model fitted the equilibrium data better than the Langmuir isotherm model. Experimental data are also evaluated in terms of kinetic characteristics of adsorption and it was found that the adsorption process for Ni+2 ions follows well pseudo-second-order kinetics. Thermodynamic functions, the change of free energy (?G°), enthalpy (?H°) and entropy (?S°) of adsorption are also calculated for Nickel (II) ions. The results show that the adsorption of the Nickel (II) ions on Iraqi Bentonite is feasible and exothermic at (20-50) °C.
The research includes studying the mechanical properties of BNTN/PAM nanocomposites under static and dynamic conditions. The BNTN/PAM nanocomposites were prepared with different weight fractions (0, 20%, 40%, 50% and 60%) by utilizing ball milling technique. Tensile strength, Charpy impact and Shore A hardness were performed to verify any improvements in these mechanical properties of nanocomposites. The results showed significant improvements in tensile, Charpy impact, Shore A hardness properties of nanocomposites at 50% weight fraction by approximately 335%, 1422%, 63% respectively. These results started decreasing after addition of 60% of nanoclays content to PAM composites. This mechanism indicates that the percentage of weight content of BNTN could affect the mechanical properties of nanocomposites.